Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal—Organic Frameworks and Polyhedra.

Metal-organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking square units M(CO) (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and cryst...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 130; no. 35; pp. 11650 - 11662
Main Authors:	Furukawa, Hiroyasu, Jaheon Kim, Ockwig, Nathan W., O'keeffe, Michael, Yaghi, Omar M.
Format:	Article
Published:	American Chemical Society 9/3/2008
Subjects:	Structural frames Geometry Linear algebra Cycles Osmosis
Online Access:	View this record in EBSCOhost