Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal—Organic Frameworks and Polyhedra.
Metal-organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking square units M(CO) (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and cryst...
| Publicado en: | Journal of the American Chemical Society Vol. 130; no. 35; pp. 11650 - 11662 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
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American Chemical Society
9/3/2008
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=34310651&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 34310651 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 9/3/2008 vid: 130 iid: 35 pid: 997 pub: American Chemical Society artinfo: ui: 34310651 10.1021/ja803783c ppf: 11650 ppct: 12 formats: tig: atl: Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal—Organic Frameworks and Polyhedra. aug: au: Furukawa, Hiroyasu Jaheon Kim Ockwig, Nathan W. O'keeffe, Michael Yaghi, Omar M. affil: Department of Chemistry and Biochemistry, Center for Reticular Chemistry at the California NanoSystems Institute, University of California, Los Angeles, California 90095-1569 Department of Chemistry, Soongsil University, Seoul 156-743, Korea Geochemistry Department, Sandia National Laboratories, Albuquerque, New Mexico 87185-0754 Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287-1604 su: Structural frames Geometry Linear algebra Cycles Osmosis sug: subj: Structural frames Geometry Linear algebra Cycles Osmosis ab: Metal-organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking square units M(CO) (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and crystal structures of 5 new MOPs and 11 new MOFs (termed MOP-14, -15, -17, -23, -24 and MOF-114, -115,-116,-117,-118,-119,-222,-601,-602,-603,-604)and show how their structures are related to the shape and functionality of the building blocks. The gas uptake behaviors of MOP-23 and MOF-601 to -603 are also presented as evidence that these structures have permanent porosity and rigid architectures. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2008 holdings: @attributes: islocal: N |
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